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Corrosion behavior of Fe–Cr–Ni based alloys exposed to molten MgCl2–KCl–NaCl salt with over-addedMg corrosion inhibitor

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1608-1619 doi: 10.1007/s11705-023-2349-1

摘要： MgCl2–NaCl–KCl salts mixture shows great potential as a high-temperature (> 700 °C) thermal energy storage material in next-generation concentrated solar power plants. Adding Mg into molten MgCl2–NaCl–KCl salt as a corrosion inhibitor is one of the most effective and cost-effective methods to mitigate the molten salt corrosion of commercial Fe–Cr–Ni alloys. However, it is found in this work that both stainless steel 310 and Incoloy 800H samples were severely corroded after 500 h immersion test at 700 °C when the alloy samples directly contacted with the over-added Mg in the liquid form. The corrosion attack is different from the classical impurity-driven corrosion in molten chloride salts found in previous work. Microscopic analysis indicates that Ni preferentially leaches out of alloy matrix due to the tendency to form MgNi2/Mg2Ni compounds. The Ni-depletion leads to the formation of a porous corrosion layer on both alloys, with the thickness around 204 µm (stainless steel 310) and 1300 µm (Incoloy 800H), respectively. These results suggest that direct contact of liquid Mg with Ni-containing alloys should be avoided during using Mg as a corrosion inhibitor for MgCl2–NaCl–KCl or other chlorides for high temperature heat storage and transfer.

关键词： concentrated solar power (CSP)     Mg corrosion inhibitor     Mg–Ni intermetallic     salt purification     thermal energy storage (TES)    

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Efficient hydrothermal deoxygenation of methyl palmitate to diesel-like hydrocarbons on carbon encapsulated Ni–Snintermetallic compounds with methanol as hydrogen donor

《化学科学与工程前沿（英文）》 2023年 第17卷 第2期   页码 139-155 doi: 10.1007/s11705-022-2217-4

摘要： Porous carbon-encapsulated Ni and Ni–Sn intermetallic compound catalysts were prepared by the one-pot extended Stöber method followed by carbonization and tested for in-situ hydrothermal deoxygenation of methyl palmitate with methanol as the hydrogen donor. During the catalyst preparation, Sn doping reduces the size of carbon spheres, and the formation of Ni–Sn intermetallic compounds restrain the graphitization, contributing to larger pore volume and pore diameter. Consequently, a more facile mass transfer occurs in carbon-encapsulated Ni–Sn intermetallic compound catalysts than in carbon-encapsulated Ni catalysts. During the in-situ hydrothermal deoxygenation, the synergism between Ni and Sn favors palmitic acid hydrogenation to a highly reactive hexadecanal that easily either decarbonylate to n-pentadecane or is hydrogenated to hexadecanol. At high reaction temperature, hexadecanol undergoes dehydrogenation–decarbonylation, generating n-pentadecane. Also, the C–C bond hydrolysis and methanation are suppressed on Ni–Sn intermetallic compounds, favorable for increasing the carbon yield and reducing the H2 consumption. The n-pentadecane and n-hexadecane yields reached 88.1% and 92.8% on carbon-encapsulated Ni3Sn2 intermetallic compound at 330 °C. After washing and H2 reduction, the carbon-encapsulated Ni3Sn2 intermetallic compound remains stable during three recycling cycles. This is ascribed to the carbon confinement that effectively suppresses the sintering and loss of metal particles under harsh hydrothermal conditions.

关键词： extended Stöber method     carbon encapsulated Ni–Sn intermetallic compounds     confinement     in-situ hydrothermal deoxygenation     hydrogenation     decarbonylation    

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Flux-free brazing of Mg-containing aluminium alloys by means of cold spraying

BOBZIN Kirsten, ZHAO Lidong, ERNST Felix, RICHARDT Katharina

《机械工程前沿（英文）》 2008年 第3卷 第4期   页码 355-359 doi: 10.1007/s11465-008-0055-9

摘要： In the present study, AlSi12 and AlSi10Cu4 were deposited onto Mg-containing aluminium alloys 6063 and 5754 by cold spraying. The influences of the two brazing alloys and spray parameters on coating formation were investigated. The microstructure of the coatings was characterized. Some coated samples were heat-treated at 590°C and 560°C in air to investigate the effect of the rupture of oxide scales on the diffusion of elements during heat-treatment. Some coated samples were brazed under argon atmosphere without any fluxes. The results show that AlSi12 had much better deposition behaviour than AlSi10Cu4. Due to the rupture of oxide scales, Cu and Si diffused into the substrate and a metallurgical bond formed between the brazing alloys and the substrates during heat-treatment. The coated samples could be brazed without any fluxes. Because the oxide scales prevented the formation of a metallurgical bond locally, the brazed samples had relatively low shear strengths of up to 43 MPa.

关键词： diffusion     metallurgical     substrate     Mg-containing aluminium     spraying    

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Electrochemical CO reduction to C products over CuZn intermetallic catalysts synthesized by electrodeposition

《能源前沿（英文）》 doi: 10.1007/s11708-023-0898-0

摘要： Electrocatalytic CO2 reduction (ECR) offers an attractive approach to realizing carbon neutrality and producing valuable chemicals and fuels using CO2 as the feedstock. However, the lack of cost-effective electrocatalysts with better performances has seriously hindered its application. Herein, a one-step co-electrodeposition method was used to introduce Zn, a metal with weak *CO binding energy, into Cu to form Cu/Zn intermetallic catalysts (Cu/Zn IMCs). It was shown that, using an H-cell, the high Faradaic efficiency of C2+ hydrocarbons/alcohols (FEC2+) could be achieved in ECR by adjusting the surface metal components and the applied potential. In suitable conditions, FEC2+ and current density could be as high as 75% and 40 mA/cm2, respectively. Compared with the Cu catalyst, the Cu/Zn IMCs have a lower interfacial charge transfer resistance and a larger electrochemically active surface area (ECSA), which accelerate the reaction. Moreover, the *CO formed on Zn sites can move to Cu sites due to its weak binding with *CO, and thus enhance the C–C coupling on the Cu surface to form C2+ products.

关键词： carbon dioxide electroreduction     electrochemistry     co-electrodeposition     intermetallic catalysts     value-added chemicals    

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Promoting hydrogen industry with high-capacity Mg-based solid-state hydrogen storage materials and systems

《能源前沿（英文）》 2023年 第17卷 第3期   页码 320-323 doi: 10.1007/s11708-023-0889-1

摘要： Promoting hydrogen industry with high-capacity Mg-based solid-state hydrogen storage materials and systems

关键词： materials systems    

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Preparation and crystallization kinetics of micron-sized Mg(OH)

Xingfu SONG, Kefeng TONG, Shuying SUN, Ze SUN, Jianguo YU

《化学科学与工程前沿（英文）》 2013年 第7卷 第2期   页码 130-138 doi: 10.1007/s11705-013-1332-7

摘要： Magnesium hydroxide is an important chemical, and is usually obtained from seawater or brine via precipitation process. The particle size distribution of magnesium hydroxide has great effects on the subsequent filtration and drying processes. In this paper, micron-sized magnesium hydroxide with high purity, large particle size and low water content in filter cake was synthesized via simple wet precipitation in a mixed suspension mixed product removal (MSMPR) crystallizer. The effects of reactant concentration, residence time and impurities on the properties of magnesium hydroxide were investigated by X-Ray diffraction (XRD), Scanning Electron Microscopy (SEM) and Malvern laser particle size analyzer. The results show that NaOH concentration and residence time have great effects on the water content and particle size of Mg(OH) . The spherical Mg(OH) with uniform diameter of about 30 μm was obtained with purity higher than 99% and water content less than 31%. Furthermore, the crystallization kinetics based on the population balance theory was studied to provide the theoretical data for industrial enlargement, and the simulation coefficients ( ) based on ASL model and C-R model are 0.9962 and 0.9972, respectively, indicating that the crystal growth rate of magnesium hydroxide can be well simulated by the size-dependent growth models.

关键词： magnesium hydroxide     precipitation     micron-sized     crystallization kinetics    

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Fatigue and impact analysis and multi-objective optimization design of Mg/Al assembled wheel considering

《机械工程前沿（英文）》 2022年 第17卷 第3期 doi: 10.1007/s11465-022-0701-7

摘要： The multi-material assembled light alloy wheel presents an effective lightweight solution for new energy vehicles, but its riveting connection remains a problem. To address this problem, this paper proposed the explicit riveting-implicit springback-implicit fatigue/explicit impact sequence coupling simulation analysis method, analyzed the fatigue and impact performance of the punching riveting connected magnesium/aluminum alloy (Mg/Al) assembled wheel, and constructed some major evaluation indicators. The accuracy of the proposed simulation method was verified by conducting physical experiments of single and cross lap joints. The punching riveting process parameters of the assembled wheel joints were defined as design variables, and the fatigue and impact performance of the assembled wheel was defined as the optimization objective. The connection-performance integration multi-objective optimization design of the assembled wheel considering riveting residual stress was designed via Taguchi experiment, grey relational analysis, analytic hierarchy process, principal component analysis, and entropy weighting methods. The optimization results of the three weighting methods were compared, and the optimal combination of design variables was determined. The fatigue and impact performance of the Mg/Al assembled wheel were effectively improved after optimization.

关键词： magnesium/aluminum assembled wheel     riveting residual stress     fatigue analysis     impact analysis     multi-objective optimization    

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The cooperation effect of Ni and Pt in the hydrogenation of acetic acid

《化学科学与工程前沿（英文）》 2022年 第16卷 第3期   页码 397-407 doi: 10.1007/s11705-021-2076-4

摘要： The catalytic hydrogenation of carboxylic acid to alcohols is one of the important strategies for the conversion of biomass. Herein, a series of Ni-doped PtSn catalysts were prepared, characterized and studied in the hydrogenation of acetic acid. The Ni dopant has a strong interaction with Pt, which promotes the hydrogen adsorption, providing an activated hydrogen-rich environment for the hydrogenation. Meanwhile, the presence of Ni also improves the Pt dispersion, giving more accessible active sites for hydrogen activation. The cooperation of Pt and Ni significantly promotes the catalytic activity of the hydrogenation of acetic acid to ethanol. As a result, the catalyst with 0.1% Ni exhibits the best reaction activity, and its space time yield is twice as that of the PtSn/SiO2 catalyst. It provides a meaningful instruction on the catalyst design for the carboxylic acid hydrogenation.

关键词： acetic acid     ethanol     hydrogenation     Pt     Ni     cooperation effect    

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Effect of process parameters on the density and porosity of laser melted AlSi10Mg/SiC metal matrix composite

Omotoyosi H. FAMODIMU, Mark STANFORD, Chike F. ODUOZA, Lijuan ZHANG

《机械工程前沿（英文）》 2018年 第13卷 第4期   页码 520-527 doi: 10.1007/s11465-018-0521-y

摘要：

Laser melting of aluminium alloy—AlSi10Mg has increasingly been used to create specialised products in various industrial applications, however, research on utilising laser melting of aluminium matrix composites in replacing specialised parts have been slow on the uptake. This has been attributed to the complexity of the laser melting process, metal/ceramic feedstock for the process and the reaction of the feedstock material to the laser. Thus, an understanding of the process, material microstructure and mechanical properties is important for its adoption as a manufacturing route of aluminium metal matrix composites. The effects of several parameters of the laser melting process on the mechanical blended composite were thus investigated in this research. This included single track formations of the matrix alloy and the composite alloyed with 5% and 10% respectively for their reaction to laser melting and the fabrication of density blocks to investigate the relative density and porosity over different scan speeds. The results from these experiments were utilised in determining a process window in fabricating near-fully dense parts.

关键词： selective laser melting     additive manufacturing     mechanical alloying     powder metallurgy     aluminium metal matrix composite    

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Catalytic hydrolysis of gaseous HCN over Cu–Ni/γ-Al

Linxia Yan, Senlin Tian, Jian Zhou, Xin Yuan

《环境科学与工程前沿（英文）》 2016年 第10卷 第6期 doi: 10.1007/s11783-016-0872-8

摘要： ? The Cu–Ni/γ-Al O catalyst was prepared to study HCN hydrolysis ? On catalyst calcined at 400°C, the HCN removal efficiency reaches a maximum. ? HCN removal is the highest at 480 min at a H O/HCN volume ratio of 150 ? The presence of CO facilitates HCN hydrolysis and increases NH production. ? O increases the HCN removal and NO production but decreases NH production GRAPHIC ABSTRACT To decompose efficiently hydrogen cyanide (HCN) in exhaust gas, g-Al O -supported bimetallic-based Cu–Ni catalyst was prepared by incipient-wetness impregnation method. The effects of the calcination temperature, H O/HCN volume ratio, reaction temperature, and the presence of CO or O on the HCN removal efficiency on the Cu–Ni/g-Al O catalyst were investigated. To examine further the efficiency of HCN hydrolysis, degradation products were analyzed. The results indicate that the HCN removal efficiency increases and then decreases with increasing calcination temperature and H O/HCN volume ratio. On catalyst calcined at 400°C, the efficiency reaches a maximum close to 99% at 480 min at a H O/HCN volume ratio of 150. The HCN removal efficiency increases with increasing reaction temperature within the range of 100°C–500°C and reaches a maximum at 500°C. This trend may be attributed to the endothermicity of HCN hydrolysis; increasing the temperature favors HCN hydrolysis. However, the removal efficiencies increases very few at 500°C compared with that at 400°C. To conserve energy in industrial operations, 400°C is deemed as the optimal reaction temperature. The presence of CO facilitates HCN hydrolysis andincreases NH production. O substantially increases the HCN removal efficiency and NO production but decreases NH production.

关键词： Hydrogen cyanide     Cu–Ni/g-Al2O3     Catalytic hydrolysis    

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Pt-Ni nanourchins as electrocatalysts for oxygen reduction reaction

Qiaowan CHANG, Yuan XU, Shangqian ZHU, Fei XIAO, Minhua SHAO

《能源前沿（英文）》 2017年 第11卷 第3期   页码 254-259 doi: 10.1007/s11708-017-0493-3

摘要： Pt-Ni bimetallic alloys with various nanostructures have shown excellent activity toward oxygen reduction reaction (ORR). The ORR activity is highly dependent on the structure of the catalyst. In this paper, Pt-Ni nanourchins were synthesized with an average size of 50 nm consisting of 10–20 nanorods and nanooctahedra by adjusting the synthesis condition. The formation of Pt-Ni nanourchins is mainly dependent on the adding order of solvents (benzyl ether, oleylamine and oleic acid). Pt-Ni nanourchins present a reasonable high ORR activity (0.81 A/mg at 0.9 V).

关键词： Pt-Ni alloys     nanourchins     oxygen reduction reaction     shape control     fuel cells    

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Current situation and development of wind power in China

BAO Nengsheng, NI Weidou

《能源前沿（英文）》 2007年 第1卷 第4期   页码 371-383 doi: 10.1007/s11708-007-0056-4

摘要： The current development of wind power in China was presented in this paper. Many regions such as Xinjiang Uygur Autonomous Region, Inner Mongolia Autonomous Region and southeast coastal region, etc. in China have abundant wind energ

关键词： Xinjiang     current development     Mongolia Autonomous     southeast coastal     Autonomous    

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Evaluation of the influence of El Niño–Southern Oscillation on air quality in southern China from long-term

《环境科学与工程前沿（英文）》 2022年 第16卷 第2期 doi: 10.1007/s11783-021-1460-0

摘要：

•Strong ENSO influence on AOD is found in southern China region.

关键词： El Niño–Southern Oscillation     Aerosol concentration     Aerosol particle size     Contribution separation     Decadal trend     Southern China    

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Emergy evaluation of polygeneration systems

WANG Lingmei, LI Zheng, NI Weidou

《能源前沿（英文）》 2007年 第1卷 第2期   页码 223-227 doi: 10.1007/s00000-007-0030-x

摘要： To expand the application range of the emergy evaluation method, an emergy evaluation index, which can reflect the particular feature of polygeneration systems, has been elaborated on the basis of energy and emergy conservation, guided by the fundamental principle of emergy analysis. With this index, the cost structure, emission effect and energy saved were all considered on the same level of importance. To exemplify, some power polygeneration systems (methanol-power generation, hydrogen-power generation) are considered using coal as the basic fuel. The results showed that emergy evaluation indices are practical for comprehensively evaluating polygeneration systems and their sustainability, which is influenced by such factors as the joining mode of polygeneration and the technologies used. The sustainability of polygeneration systems, which work on an appropriate ratio of fuel-to-electric power basis, is higher than that of singular production systems.

关键词： fuel-to-electric     sustainability     importance     polygeneration     practical    

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Adsorptive behaviors of humic acid onto freshly prepared hydrous manganese dioxides

LIU Ruiping, LI Guibai, YANG Yanling, HE Wenjie, HAN Hongda

《环境科学与工程前沿（英文）》 2007年 第1卷 第2期   页码 240-245 doi: 10.1007/s11783-007-0041-1

摘要： This study focused on the adsorptive behaviors of humic acid onto freshly prepared hydrous MnO(s) (δMnO), and investigated the feasibility of employing δMnO for humic acid removal from drinking water. Effects of such parameters as molecular mass of humic acid, kinds of divalent cations on adsorptive behaviors and possible mechanisms involved were investigated. This study indicated that humic acid with higher molecular mass exhibited more tendency of adsorbing onto &MnO than that with lower molecular mass. Ca facilitated more humic acid adsorption than Mg; UV-Vis spectra analysis indicated higher capabilities of Ca coordinating with acidic functional groups of humic acid than that of Mg. Additionally, ζ potential characterization indicated that Ca showed higher potential of increasing ζ potential of &MnO than Mg. Ca of 1.0 mmol/L increased ζ potential of δMnO

关键词： Mg     molecular     functional     UV-Vis spectra     prepared hydrous    

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标题 作者 时间 类型 操作

Corrosion behavior of Fe–Cr–Ni based alloys exposed to molten MgCl2–KCl–NaCl salt with over-addedMg corrosion inhibitor

期刊论文

Efficient hydrothermal deoxygenation of methyl palmitate to diesel-like hydrocarbons on carbon encapsulated Ni–Snintermetallic compounds with methanol as hydrogen donor

期刊论文

Flux-free brazing of Mg-containing aluminium alloys by means of cold spraying

BOBZIN Kirsten, ZHAO Lidong, ERNST Felix, RICHARDT Katharina

期刊论文

Electrochemical CO reduction to C products over CuZn intermetallic catalysts synthesized by electrodeposition

期刊论文

Promoting hydrogen industry with high-capacity Mg-based solid-state hydrogen storage materials and systems

期刊论文

Preparation and crystallization kinetics of micron-sized Mg(OH)

Xingfu SONG, Kefeng TONG, Shuying SUN, Ze SUN, Jianguo YU

期刊论文

Fatigue and impact analysis and multi-objective optimization design of Mg/Al assembled wheel considering

期刊论文

The cooperation effect of Ni and Pt in the hydrogenation of acetic acid

期刊论文

Effect of process parameters on the density and porosity of laser melted AlSi10Mg/SiC metal matrix composite

Omotoyosi H. FAMODIMU, Mark STANFORD, Chike F. ODUOZA, Lijuan ZHANG

期刊论文

Catalytic hydrolysis of gaseous HCN over Cu–Ni/γ-Al

Linxia Yan, Senlin Tian, Jian Zhou, Xin Yuan

期刊论文

Pt-Ni nanourchins as electrocatalysts for oxygen reduction reaction

Qiaowan CHANG, Yuan XU, Shangqian ZHU, Fei XIAO, Minhua SHAO

期刊论文

Current situation and development of wind power in China

BAO Nengsheng, NI Weidou

期刊论文

Evaluation of the influence of El Niño–Southern Oscillation on air quality in southern China from long-term

期刊论文

Emergy evaluation of polygeneration systems

WANG Lingmei, LI Zheng, NI Weidou

期刊论文

Adsorptive behaviors of humic acid onto freshly prepared hydrous manganese dioxides

LIU Ruiping, LI Guibai, YANG Yanling, HE Wenjie, HAN Hongda

期刊论文